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Managed fusion: Aromatic substrates with oxygen†and nitrogenâ€made up of substituents undergo oxidative coupling with alkynes and alkenes below rhodium catalysis through regioselective CH bond cleavage.
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N-heterocyclic carbenes exchange hydrogen-bonding companions via two pathways. For much less basic carbenes a dissociation occurs to supply a free carbene that could meet up with a fresh hydrogen-bond-donor molecule. More basic carbenes kind a hydrogen bond with a new lover before dissociation, steering clear of the development of the free carbene.